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5.4. Oxidation no.-1 the properties of the halides, p114

Procedure 1

1.     take 6 test-tubes and a holder, 0.1M solutions of K/Na halides into beakers

2.     add every halide to 2 tubes, to half add ammonia and note colour.

3.     leave other half for sunlight for 1hour

2. 1. Moisten stips of filterpaper with lead(II) ethanoate and potassium dicromate.(just put them ready)

2.     Take now solid halide salts and put 0.1g (fills round bit) to 12 test-tubes, add H2SO4 and warm if necessary.

3.     Add 10drops of conc. H2SO4 and test with moistened filter paper

4.     Add 10drops of conc. H3PO4 and test with moistened filter paper.

3. 1. collect the gas into apparatus as in fig. p115 (dry testtubes, solid phosphoric)

Use 6 testtubes, bunsen to warm, 2g of halide and phosphoric and corks to prevent escaping.

Invert a tube in water and remove cork to observe solubility. Residue is air.

Take a glass rod dipped into conc. ammonia and hold near the mouth of test-tube

Heath the end of nicrome wire or glass rod and put into the gas.

 

 

 

 

 

 

 

 

Operation

Cl-

Br-

I-

Observation

Equation

Add AgNO3

white ppt

cream ppt

yellow pt

precipit

Ag+AgH(s)

add ammonia

soluble

soso

not

prec.disappears

NH4Ha(aq/s)

Leave AgHal to sunlight

purplgrey

greenyelo

no

colourchange

Ag(s)+H(g)

When conc.H2SO4 is added

HCl

SO2 Br2

SO2 Br2

H2SO4 reducer

H H2O SO2

test with lead(II) ethanoate

white ppt

yellow pt

no(yellow

ppt

PbCl2(s)

test with potassium dicromate

no             |reduced due to SO2

When conc.H3PO4 is added

HCl

HBr

HBr

H3PO4 not redu

Na3PO4

test with lead(II) ethanoate

white

yellow

yellow

test with potassium dicromate

no

colour of halide

yellow

yellow

pink

solubility in water

yes

soso

no

reaction with ammonia

white gas

yellow ga

yellow ga

reacts

NH4Hal(s)

Reaction of heath

 

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